Synthesis and characterization of some transition metal complexes with new Schiff base ligand (ABATSC)

Abstract

Six metal complexes of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) with new
Schiff base p-(N,N-dimethyl amino benzaldehyde) acetopheneden thiosemicarbazone
(ABATSC) have been synthesized and characterized by elemental analysis, magnetic
susceptibility, molar conductance, in addition of IR and electronic spectra. The result
show that the functional groups was (–C=S) and (-CH=N-). It has been found that
(ABATSC) act as a natural bidentate ligand . The suggest geometry of the complexes
appears to be octahedral and expected for non electrolyte.